Graphyne Nanotubes as Promising Sodium-Ion Battery Anodes
نویسندگان
چکیده
Sodium-ion batteries (SIBs) are promising candidates for the replacement of lithium-ion (LIBs) because sodium’s abundant reserves and lower cost sodium compared to lithium. This is a topic interest developing novel anodes with high storage capacity. Owing their low cost, stability, conductivity, carbon-based materials have been studied extensively. However, sp2-C based carbon low-rate capacities. Intensive density functional theory calculations implemented explore applicability α, β, γ graphyne nanotubes (αGyNTs, βGyNTs, γGyNTs, respectively) as SIB anodes. Results suggest that (3, 0)-αGyNT, (2, 2)-βGyNT, (4, 0)-γGyNT have, respectively, maximum Na capacities 1535, 1302, 1001 mAh/g, which exceeds largest reported value (N-doped graphene foams 852.6 mAh/g capacity). It was determined αGyNTs capacity three types they possess specific surface area. Moreover, larger pores βGyNTs allow easier diffusion penetration atoms those could result in better rate
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ژورنال
عنوان ژورنال: Catalysts
سال: 2022
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal12060670